Pineville is a suburban town in the southernmost portion of Mecklenburg County, North Carolina, United States. Part of the Charlotte metropoli…Pineville is a suburban town in the southernmost portion of Mecklenburg County, North Carolina, United States. Part of the Charlotte metropolitan area, it is situated in the Waxhaws region between Charlotte and Fort Mill. As of the 2020 census, Pineville had a population of 10,602, up from 7,479 in 2010.